Synthesis and Characterization Fe Doped BaBi4Ti4O15 Prepared via Molten Salt Method

Nurcahyaningtyas, Dwi and Prasetyo, Anton ORCID: https://orcid.org/0000-0003-1575-8634 (2024) Synthesis and Characterization Fe Doped BaBi4Ti4O15 Prepared via Molten Salt Method. AIP Conference Proceedings, 3106 (1). ISSN 0094-243X

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Abstract

The four-layer Aurivillius compound BaBi4Ti4O15 is reportedly applied as photocatalyst material with a band
gap energy of 3.2 eV (387.5 nm). As a result, it worksin the ultraviolet light range. The strategy to expand its work function
is to decrease the band gap energy by doped with metal elements like Fe atoms. In this research, we synthesised Fe-doped
BaBi4Ti4O15 (BaBi4Ti3.95Fe0.05O15; BaBi4Ti3.90Fe0.1O15; BaBi4Ti3.85Fe0.15O15; and BaBi4Ti3.80Fe0.2O15) with the purposes to decreases its band gap energy. The diffractogram of samples showed the doped BaBi4Ti4O15 compound was successfully formed and had no impurity phase with space group A21am. Micrograph scanning electron microscopy (SEM) showed plate-like morphology particles and still found agglomeration occurs. The result calculation of Kubelka-Munk showed that Fe doped can decrease the band gap energy of BaBi4Ti4O15.

Item Type: Journal Article
Keywords: BaBi4Ti3O12; molten salt synthesis
Subjects: 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030203 Inorganic Green Chemistry
03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030206 Solid State Chemistry
Divisions: Faculty of Mathematics and Sciences > Department of Chemistry
Depositing User: Dr Anton Prasetyo
Date Deposited: 10 Jun 2024 08:37

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